Solvent Deuterium Isotope Effects On The Infrared Spectra of Some Anions.
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Abdul Rasoul, Faik Ali. (1979) Solvent Deuterium Isotope Effects On The Infrared Spectra of Some Anions. Doctoral thesis, University of Surrey (United Kingdom)..
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Abstract
The infrared spectra from 800-1600 cm-1 of 28 anions (inorganic and organic) not containing hydroxyl group have been obtained in H2O and D2O. A significant solvent deuterium isotope shift up to 23 cm-1 occurs in most cases. Most of the shifts were negative (vH2O-vD2O negative), but the pyramidal and tetrahedral anions gave positive shifts. The shifts do not appear to have a simple interpretation; hydrogen bonding is clearly important, but other factors, such as the influence of the anions on the solvent baseline, must play a part.
| Item Type: | Thesis (Doctoral) |
|---|---|
| Divisions : | Theses |
| Authors : | Abdul Rasoul, Faik Ali. |
| Date : | 1979 |
| Additional Information : | Thesis (M.Phil.)--University of Surrey (United Kingdom), 1979. |
| Depositing User : | EPrints Services |
| Date Deposited : | 06 May 2020 14:38 |
| Last Modified : | 06 May 2020 14:46 |
| URI: | http://epubs.surrey.ac.uk/id/eprint/856343 |
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