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Large‐Scale Surfactant Exfoliation of Graphene and Conductivity‐Optimized Graphite Enabling Wireless Connectivity

Large, Matthew J., Ogilvie, Sean P., Amorim Graf, Aline, Lynch, Peter J., O'Mara, Marcus A., Waters, Thomas, Jurewicz, Izabela, Salvage, Jonathan P. and Dalton, Alan B. (2020) Large‐Scale Surfactant Exfoliation of Graphene and Conductivity‐Optimized Graphite Enabling Wireless Connectivity Advanced Materials Technologies, 2000284.

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Graphene and other graphitic materials are suggested as a route to cheap, high‐performance, environmentally‐sustainable electronic devices owing to their almost unique combination of properties. Liquid‐phase exfoliation is a family of shear‐based techniques that produce dispersions of nanosheets from bulk layered material crystallites. High‐quality nanosheets of graphene can be produced in solvents or surfactant dispersions; however the lateral size of these sheets limits the network transport properties observed in printed films. A high‐throughput, industrially‐scalable aqueous process for the production of graphene and related layered nanomaterials is presented. By considering not only the exfoliation process, but also the size selection and deposition processes, printable graphitic nanoparticulate materials with conductivities up to 50 000 S m−1 are demonstrated. This value is ten times larger than is typically obtained for few‐layer graphene produced by liquid‐phase exfoliation. The size selection process is critical to obtaining the maximum conductivity of deposited films, with an optimized nanographite having greater performance than few‐layer graphene or graphite that is processed and used without size selection. Building on these results a radio‐frequency antenna application is demonstrated, which is competitive with the state‐of‐the‐art, and a route to recycling of such printed short‐lifetime electronic devices to lower the environmental impact is discussed.

Item Type: Article
Divisions : Faculty of Engineering and Physical Sciences > Physics
Authors :
Large, Matthew J.
Ogilvie, Sean P.
Amorim Graf, Aline
Lynch, Peter J.
O'Mara, Marcus A.
Waters, Thomas
Salvage, Jonathan P.
Dalton, Alan B.
Date : 26 May 2020
Funders : Advanced Material Development Ltd
DOI : 10.1002/admt.202000284
Copyright Disclaimer : © 2020 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Uncontrolled Keywords : Antennae; Graphene; Liquid-phase exfoliation; Printing; Scalability
Depositing User : Clive Harris
Date Deposited : 04 Jun 2020 19:26
Last Modified : 04 Jun 2020 19:26

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