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Solvent Deuterium Isotope Effects On The Infrared Spectra of Some Anions.

Abdul Rasoul, Faik Ali. (1979) Solvent Deuterium Isotope Effects On The Infrared Spectra of Some Anions. Doctoral thesis, University of Surrey (United Kingdom)..

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Abstract

The infrared spectra from 800-1600 cm-1 of 28 anions (inorganic and organic) not containing hydroxyl group have been obtained in H2O and D2O. A significant solvent deuterium isotope shift up to 23 cm-1 occurs in most cases. Most of the shifts were negative (vH2O-vD2O negative), but the pyramidal and tetrahedral anions gave positive shifts. The shifts do not appear to have a simple interpretation; hydrogen bonding is clearly important, but other factors, such as the influence of the anions on the solvent baseline, must play a part.

Item Type: Thesis (Doctoral)
Divisions : Theses
Authors : Abdul Rasoul, Faik Ali.
Date : 1979
Additional Information : Thesis (M.Phil.)--University of Surrey (United Kingdom), 1979.
Depositing User : EPrints Services
Date Deposited : 06 May 2020 14:38
Last Modified : 06 May 2020 14:46
URI: http://epubs.surrey.ac.uk/id/eprint/856343

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