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Al–H σ-bond coordination: expanded ring carbene adducts of AlH3 as neutral bi- and tri-functional donor ligands

Abdalla, Joseph A. B., Riddlestone, Ian M., Tirfoin, Remi, Phillips, Nicholas, Bates, Joshua I. and Aldridge, Simon (2013) Al–H σ-bond coordination: expanded ring carbene adducts of AlH3 as neutral bi- and tri-functional donor ligands Chemical Communications, 49 (49). pp. 5547-5549.

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Abstract

Thermally robust expanded ring carbene adducts of AlH3 have been synthesized with a view to probing their ligating abilities via Al–H σ-bond coordination. While κ2 binding to the 14-electron [Mo(CO)4] fragment is readily demonstrated, interaction with [Mo(CO)3] results in μ:κ1,κ1 and μ:κ2,κ2 bridging linkages rather than terminal κ3 binding.

Item Type: Article
Divisions : Faculty of Engineering and Physical Sciences > Chemistry
Authors :
NameEmailORCID
Abdalla, Joseph A. B.
Riddlestone, Ian M.i.riddlestone@surrey.ac.uk
Tirfoin, Remi
Phillips, Nicholas
Bates, Joshua I.
Aldridge, Simon
Date : 21 June 2013
DOI : 10.1039/C3CC42342E
Depositing User : Clive Harris
Date Deposited : 25 Jun 2019 08:26
Last Modified : 06 Jul 2019 05:27
URI: http://epubs.surrey.ac.uk/id/eprint/852074

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