University of Surrey

Test tubes in the lab Research in the ATI Dance Research

Extending the Chain: Synthetic, Structural, and Reaction Chemistry of a BN Allenylidene Analogue†

Niemeyer, J., Addy, D.A., Riddlestone, Ian, Kelly, M., Thompson, A.L., Vidovic, D. and Aldridge, S. (2011) Extending the Chain: Synthetic, Structural, and Reaction Chemistry of a BN Allenylidene Analogue† Angewandte Chemie - International Edition, 50 (38). pp. 8908-8911.

Full text not available from this repository.

Abstract

α versus γ: [CpFe(CO)(PCy3)(BNCMes2)]+, synthesized by halide abstraction, represents the first example of a BN allenylidene analogue, and features an unsaturated MBNC π system. Although DFT calculations show significant LUMO amplitude at the γ (carbon) position, primary reactivity towards nucleophiles occurs at the sterically less hindered α (boron) center.

Item Type: Article
Divisions : Faculty of Engineering and Physical Sciences > Chemistry
Authors :
NameEmailORCID
Niemeyer, J.
Addy, D.A.
Riddlestone, Iani.riddlestone@surrey.ac.uk
Kelly, M.
Thompson, A.L.
Vidovic, D.
Aldridge, S.
Date : 12 September 2011
Funders : Engineering and Physical Sciences Research Council (EPSRC)
DOI : 10.1002/anie.201103757
Uncontrolled Keywords : Allenylidenes; Boron ligands; Borylene; Halide abstraction; Iron
Depositing User : Clive Harris
Date Deposited : 24 Jun 2019 14:54
Last Modified : 24 Jun 2019 14:54
URI: http://epubs.surrey.ac.uk/id/eprint/852035

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year


Information about this web site

© The University of Surrey, Guildford, Surrey, GU2 7XH, United Kingdom.
+44 (0)1483 300800