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Cooperative bond activation and catalytic reduction of carbon dioxide at a group 13 metal center

Abdalla, J.A.B., Riddlestone, Ian M., Tirfoin, R. and Aldridge, S. (2015) Cooperative bond activation and catalytic reduction of carbon dioxide at a group 13 metal center Angewandte Chemie - International Edition, 54 (17). pp. 5098-5102.

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Abstract

A single‐component ambiphilic system capable of the cooperative activation of protic, hydridic and apolar HX bonds across a Group 13 metal/activated β‐diketiminato (Nacnac) ligand framework is reported. The hydride complex derived from the activation of H2 is shown to be a competent catalyst for the highly selective reduction of CO2 to a methanol derivative. To our knowledge, this process represents the first example of a reduction process of this type catalyzed by a molecular gallium complex.

Item Type: Article
Divisions : Faculty of Engineering and Physical Sciences > Chemistry
Authors :
NameEmailORCID
Abdalla, J.A.B.
Riddlestone, Ian M.i.riddlestone@surrey.ac.uk
Tirfoin, R.
Aldridge, S.
Date : 15 April 2015
DOI : 10.1002/anie.201500570
Uncontrolled Keywords : β‐diketiminate; Bond activation; Carbon dioxide; Cooperative reactivity; Gallium
Depositing User : Clive Harris
Date Deposited : 24 Jun 2019 10:21
Last Modified : 24 Jun 2019 10:54
URI: http://epubs.surrey.ac.uk/id/eprint/852021

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