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Taming the Cationic Beast: Novel Developments in the Synthesis and Application of Weakly Coordinating Anions

Riddlestone, Ian M., Kraft, A., Schaefer, J. and Krossing, I. (2018) Taming the Cationic Beast: Novel Developments in the Synthesis and Application of Weakly Coordinating Anions Angewandte Chemie - International Edition, 57 (43). pp. 13982-14024.

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Abstract

This Review gives a comprehensive overview of the most topical weakly coordinating anions (WCAs) and contains information on WCA design, stability, and applications. As an update to the 2004 review, developments in common classes of WCA are included. Methods for the incorporation of WCAs into a given system are discussed and advice given on how to best choose a method for the introduction of a particular WCA. A series of starting materials for a large number of WCA precursors and references are tabulated as a useful resource when looking for procedures to prepare WCAs. Furthermore, a collection of scales that allow the performance of a WCA, or its underlying Lewis acid, to be judged is collated with some advice on how to use them. The examples chosen to illustrate WCA developments are taken from a broad selection of topics where WCAs play a role. In addition a section focusing on transition metal and catalysis applications as well as supporting electrolytes is also included.

Item Type: Article
Divisions : Faculty of Engineering and Physical Sciences > Chemistry
Authors :
NameEmailORCID
Riddlestone, Ian M.i.riddlestone@surrey.ac.uk
Kraft, A.
Schaefer, J.
Krossing, I.
Date : 16 October 2018
Funders : European Research Council (ERC)
DOI : 10.1002/anie.201710782
Grant Title : UniChem
Uncontrolled Keywords : Catalysis; Functional materials; Polymerization; Weakly coordinating anions
Additional Information : No further action
Depositing User : Clive Harris
Date Deposited : 17 Jun 2019 15:19
Last Modified : 17 Jun 2019 15:19
URI: http://epubs.surrey.ac.uk/id/eprint/852012

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