University of Surrey

Test tubes in the lab Research in the ATI Dance Research

Structure and properties of a BEDT-TTF-based organic conductor with a ferrocene-based magnetic anion octamethylferrocenedisulfonate

Akutsu, H, Hashimoto, R, Yamada, J, Nakatsuji, S, Turner, Scott and Nakazawa, Y (2018) Structure and properties of a BEDT-TTF-based organic conductor with a ferrocene-based magnetic anion octamethylferrocenedisulfonate European Journal of Inorganic Chemistry, 2018 (27). pp. 3249-3252.

[img]
Preview
Text
__homes.surrey.ac.uk_home_.System_Desktop_Akutsu_et_al-2018-European_Journal_of_Inorganic_Chemistry.pdf - Accepted version Manuscript

Download (2MB) | Preview

Abstract

The structure and properties of a new semiconducting BEDT-TTF-based charge-transfer salt containing the magnetic monoanion octamethylferrocenedisulfonate (–O3SC5( CH3)4Fe+C5(CH3)4-SO3 – (ofds)), -(BEDT-TTF)5(ofds)2 is described (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene). The salt is a semiconductor with RT = 5.6  103 ·cm and Ea = 0.11 eV. There are two types of spins not only on the ferrocenyl parts but also the 2D donor layers. The former and latter spins obey Curie-Weiss (C = 0.721 emu K mol-1and  = -5.5 K) and 2D Heisenberg (J2DH = - 80.3 K) models, respectively.

Item Type: Article
Divisions : Faculty of Engineering and Physical Sciences > Chemistry
Authors :
NameEmailORCID
Akutsu, H
Hashimoto, R
Yamada, J
Nakatsuji, S
Turner, ScottS.S.Turner@surrey.ac.uk
Nakazawa, Y
Date : 22 May 2018
DOI : 10.1002/ejic.201800482
Copyright Disclaimer : This is the peer reviewed version of the following article: Hiroki Akutsu, Ryuichiro Hashimoto, Jun‐ich Yamada, Shin'ichi Nakatsuji, Scott S. Turner,and Yasuhiro Nakazawa, Structure and Properties of a BEDT‐TTF‐Based Organic Conductor with a Ferrocene‐Based Magnetic Anion Octamethylferrocenedisulfonate. DOI: 10.1002/ejic.201800482, which has been published in final form at https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201800482. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions
Depositing User : Melanie Hughes
Date Deposited : 04 Jul 2018 12:07
Last Modified : 16 Jul 2019 02:08
URI: http://epubs.surrey.ac.uk/id/eprint/848649

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year


Information about this web site

© The University of Surrey, Guildford, Surrey, GU2 7XH, United Kingdom.
+44 (0)1483 300800