University of Surrey

Test tubes in the lab Research in the ATI Dance Research

Some nitrosyl compounds of ruthenium.

Fairey, Michael Benjamin. (1962) Some nitrosyl compounds of ruthenium. Doctoral thesis, University of Surrey (United Kingdom)..

[img]
Preview
Text
10804727.pdf
Available under License Creative Commons Attribution Non-commercial Share Alike.

Download (7MB) | Preview

Abstract

The work to be described in this thesis may be considered in three parts, each relating to a particular aspect of the infrared spectroscopy of some ruthenium nitrosyls. In the first part the preparation of a number of compounds of the general type RuNOHal[3]L[2] is described, where L may be a donor ligand from Group V or VI. Some of these compounds are described for the first time. They are used in an attempt to relate variations in structure with changes in the nitrosyl stretching frequency. During the course of these preparations it was noted that with the exception of amine ligands, the synthesis of compounds containing more than two neutral ligands was extremely difficult. All the compounds were found to be diamagnetic, as would be expected from considerations outlined in the Introduction. The second part consists of an infrared study of the well characterised tetrammines [RuNO(NH[3])[4]]Y Hal[2,3] where Y = hal, -OH, H[2]O. A complete study of the spectra has been made, and the effect of the negative ligands investigated. The compounds were deuterated by hydrogen exchange with heavy water, and the results of deuteration used to assist the assignments. This work is described in Section IV. In the final part ( Section VI ) the effect of solvents on the nitrosyl stretching frequency is examined. In all cases an increase in frequency is found as the polarity of the solvent rises within a related group of solvents. An explanation of the effect based on a dipole-dipole interaction between the solvent and the nitrosyl group is proposed.

Item Type: Thesis (Doctoral)
Divisions : Theses
Authors :
NameEmailORCID
Fairey, Michael Benjamin.
Date : 1962
Contributors :
ContributionNameEmailORCID
http://www.loc.gov/loc.terms/relators/THS
Additional Information : Thesis (Ph.D.)--University of Surrey (United Kingdom), 1962.
Depositing User : EPrints Services
Date Deposited : 22 Jun 2018 14:27
Last Modified : 06 Nov 2018 16:54
URI: http://epubs.surrey.ac.uk/id/eprint/848222

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year


Information about this web site

© The University of Surrey, Guildford, Surrey, GU2 7XH, United Kingdom.
+44 (0)1483 300800