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Part 1: The synthesis of optically active metryl ethyl N-butyl methane and a study of its optical properties. Part 2: A study of some replacement reactions of optically active alphagamma-dimethylallyl alcohol and some of its derivatives.

Platt, Bertie C. (1940) Part 1: The synthesis of optically active metryl ethyl N-butyl methane and a study of its optical properties. Part 2: A study of some replacement reactions of optically active alphagamma-dimethylallyl alcohol and some of its derivatives. Doctoral thesis, University of Surrey (United Kingdom)..

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Abstract

Part I. The preparation and optical resolutions of y-methyl-n-heptane has been undertaken and the effect of solvents on its rotatory powers studied. The hydrocarbon was chosen since it possesses no polar groups which might disturb solvent influences. A review of the theories dealing with the effect of solvents on rotatory powers is presented. The required hydrocarbon was obtained from ethyl-n-butyl acetic acid; this was first resolved, converted via its ethyl ester to B-ethyl-n-hexanol and the required optically active hydrocarbon was obtained by reduction of the corresponding iodide. The racemisation of carboxylic esters in the presence of alkali is reviewed. Drude equations have been calculated for ethyl-n-butyl acetic acid, its ethyl ester, and also for B-ethyl-n-hexanol. Part II. The peculiar properties of (-)-alphagamma-dimethylallyl alcohol obtained by hydrolysis of (-)-alphagamma-dimethylallyl chloride which is in turn obtained from (+)-alphagamma-dimethylallyl alcohol base have been investigated.

Item Type: Thesis (Doctoral)
Divisions : Theses
Authors :
NameEmailORCID
Platt, Bertie C.
Date : 1940
Contributors :
ContributionNameEmailORCID
http://www.loc.gov/loc.terms/relators/THS
Additional Information : Thesis (Ph.D.)--University of Surrey (United Kingdom), 1940.
Depositing User : EPrints Services
Date Deposited : 22 Jun 2018 13:57
Last Modified : 06 Nov 2018 16:53
URI: http://epubs.surrey.ac.uk/id/eprint/847754

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