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Some complexes of transition metals with substituted anilines.

Butcher, Anthony Vincent. (1968) Some complexes of transition metals with substituted anilines. Doctoral thesis, University of Surrey (United Kingdom)..

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Abstract

The preparation and properties of some nickel(II) and cobalt(II) complexes with substituted anilines are described. Analytical, magnetic and spectral data are used to elucidate the structures of the complexes. The role of polyatomic anions in the complexes has been determined from their infrared spectra. Tetrafluoroborate ion is reluctant to coordinate in this system and only complexes of the type [Ni (aniline)6] (BF4)2 are obtained. In contrast, coordination of perchlorate ion in complexes of the type trans-[Ni (aniline)4(ClO4)2] is found and a number of spectral parameters for the complexes are given. Complexes of nickel cyanate, thiocyanate and selenocyanate are described and it is shown that the type of complex obtained with these salts is strongly dependent on the position of the substituent in the aniline ligand. The thermogravimetric behaviour of some of the complexes has been investigated. Electronic and infrared spectral measurements have been carried out on a number of previously reported nickel and cobalt halide complexes. The far infrared spectra (400-30 om-1) of the complexes prepared here are given and the results are discussed in terms of Group Theory.

Item Type: Thesis (Doctoral)
Divisions : Theses
Authors :
NameEmailORCID
Butcher, Anthony Vincent.UNSPECIFIEDUNSPECIFIED
Date : 1968
Contributors :
ContributionNameEmailORCID
http://www.loc.gov/loc.terms/relators/THSUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Depositing User : EPrints Services
Date Deposited : 09 Nov 2017 12:11
Last Modified : 09 Nov 2017 14:39
URI: http://epubs.surrey.ac.uk/id/eprint/842900

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