University of Surrey

Test tubes in the lab Research in the ATI Dance Research

The electro-oxidation of N,N-dimethyl-p-toluidine in acetonitrile: A microdisk voltammetry study

Rees, NV, Klymenko, OV, Compton, RG and Oyama, M (2002) The electro-oxidation of N,N-dimethyl-p-toluidine in acetonitrile: A microdisk voltammetry study Journal of Electroanalytical Chemistry, 531 (1). pp. 33-42.

Full text not available from this repository.

Abstract

The oxidative dimerisation reaction of N,N-dimethyl-p-toluidine (DMT) in acetonitrile was studied by cyclic voltammetry using a range of concentrations from 1 to 70 mM at microdisk electrodes of radii 10, 12.5, and 50 μm using scan rates from 20 mV s-1 to 6 V s-1. Theory was developed to simulate the following mechanism using the ADI method and comparison made to experimental voltammograms.The mechanism was found to be consistent with the observed data under all experimental conditions employed. The following rate constants were inferred: k1=(5.9±2.2)×105 cm3 mol-1 s-1, k-1≈0, and k2=(9.2±3.8)×108 cm3 mol-1 s-1. © 2002 Elsevier Science B.V. All rights reserved.

Item Type: Article
Authors :
NameEmailORCID
Rees, NVUNSPECIFIEDUNSPECIFIED
Klymenko, OVo.klymenko@surrey.ac.ukUNSPECIFIED
Compton, RGUNSPECIFIEDUNSPECIFIED
Oyama, MUNSPECIFIEDUNSPECIFIED
Date : 9 August 2002
Identification Number : https://doi.org/10.1016/S0022-0728(02)01054-9
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 13:57
Last Modified : 17 May 2017 15:14
URI: http://epubs.surrey.ac.uk/id/eprint/840968

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year


Information about this web site

© The University of Surrey, Guildford, Surrey, GU2 7XH, United Kingdom.
+44 (0)1483 300800