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The theory of electrodeposition in the presence of forced convection: Transport controlled nucleation of hemispheres

Hyde, ME, Klymenko, OV and Compton, RG (2002) The theory of electrodeposition in the presence of forced convection: Transport controlled nucleation of hemispheres Journal of Electroanalytical Chemistry, 534 (1). pp. 13-17.

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Abstract

A new equation to describe the diffusion controlled nucleation of hemispherical centres under conditions of forced convection is derived, in a manner similar to that of the Scharifker and Mostany equation (J. Electroanal. Chem. 177 (1984) 13). It has been shown that the transients measured under these conditions should show a monotonically rising transient, followed by convergence to a limiting current. The accuracy and validity of the model is tested by comparison with experimental data obtained using a 5 mM Co/Co2+ system, sonicated at 66 W cm-2. Excellent fits are obtained, and the parameters derived are in agreement with those derived from independent experiments. © 2002 Elsevier Science B.V. All rights reserved.

Item Type: Article
Authors :
NameEmailORCID
Hyde, MEUNSPECIFIEDUNSPECIFIED
Klymenko, OVo.klymenko@surrey.ac.ukUNSPECIFIED
Compton, RGUNSPECIFIEDUNSPECIFIED
Date : 4 October 2002
Identification Number : 10.1016/S0022-0728(02)01103-8
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 13:57
Last Modified : 17 May 2017 15:14
URI: http://epubs.surrey.ac.uk/id/eprint/840965

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