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The electrochemical oxidation of N,N-diethyl-p-phenylenediamine in DMF and analytical applications. Part I: Mechanistic study

Klymenko, OV, Giovanelli, D, Lawrence, NS, Rees, NV, Jiang, L, Jones, TGJ and Compton, RG (2003) The electrochemical oxidation of N,N-diethyl-p-phenylenediamine in DMF and analytical applications. Part I: Mechanistic study Electroanalysis, 15 (11). pp. 949-960.

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Abstract

The electrochemical oxidation of N,N-diethyl-p-phenylenediamine in dimethylformamide has been studied at platinum and gold microdisk electrodes of various radii between 6.7 and 66 μm. The voltammetric responses revealed two electrochemically reversible waves the second of which becomes larger at higher concentrations and bigger electrode radii. The voltammetric signals have been modelled and the electrochemical oxidation reaction is not inconsistent with an ECrevECE reaction. Kinetic parameters are reported.

Item Type: Article
Authors :
NameEmailORCID
Klymenko, OVo.klymenko@surrey.ac.ukUNSPECIFIED
Giovanelli, DUNSPECIFIEDUNSPECIFIED
Lawrence, NSUNSPECIFIEDUNSPECIFIED
Rees, NVUNSPECIFIEDUNSPECIFIED
Jiang, LUNSPECIFIEDUNSPECIFIED
Jones, TGJUNSPECIFIEDUNSPECIFIED
Compton, RGUNSPECIFIEDUNSPECIFIED
Date : 1 July 2003
Identification Number : https://doi.org/10.1002/elan.200390115
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 13:57
Last Modified : 17 May 2017 15:14
URI: http://epubs.surrey.ac.uk/id/eprint/840959

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