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Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones

Rees, NV, Clegg, AD, Klymenko, OV, Coles, BA and Compton, RG (2004) Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones Journal of Physical Chemistry B, 108 (34). pp. 13047-13051.

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Abstract

Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and the predictions are compared to experimental measurements.

Item Type: Article
Authors :
NameEmailORCID
Rees, NVUNSPECIFIEDUNSPECIFIED
Clegg, ADUNSPECIFIEDUNSPECIFIED
Klymenko, OVo.klymenko@surrey.ac.ukUNSPECIFIED
Coles, BAUNSPECIFIEDUNSPECIFIED
Compton, RGUNSPECIFIEDUNSPECIFIED
Date : 26 August 2004
Identification Number : https://doi.org/10.1021/jp0403821
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 13:57
Last Modified : 17 May 2017 15:14
URI: http://epubs.surrey.ac.uk/id/eprint/840946

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