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Modelling homogeneous kinetics in the double channel electrode

Thompson, M, Klymenko, OV and Compton, RG (2005) Modelling homogeneous kinetics in the double channel electrode Journal of Electroanalytical Chemistry, 576 (2). pp. 333-338.

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Concentration profiles of electrochemically generated species are simulated in a channel flow cell containing two electrodes, where a species produced upstream at the generator electrode is detected downstream by the collector electrode. The model is extended for simulation of the currents produced at each electrode when a homogeneous reaction takes place involving the species produced at the generator. For specific cell dimensions and homogeneous mechanism there is a maximum rate constant for the homogeneous reaction that can be measured using the double electrode system, which is a function of the flow rate, the cell geometry and the relative concentrations of the species initially present. The results presented function as a guide to selecting suitable cell geometries and experimental parameters in order to measure homogeneous kinetics using the double channel electrode. © 2004 Elsevier B.V. All rights reserved.

Item Type: Article
Authors :
Date : 1 March 2005
Identification Number : 10.1016/j.jelechem.2004.10.029
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 13:57
Last Modified : 17 May 2017 15:14

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