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Comparative solubilisation of potassium carbonate, sodium bicarbonate and sodium carbonate in hot dimethylformamide: application of cylindrical particle surface-controlled dissolution theory.

Forryan, CL, Compton, RG, Klymenko, OV, Brennan, CM, Taylor, CL and Lennon, M (2006) Comparative solubilisation of potassium carbonate, sodium bicarbonate and sodium carbonate in hot dimethylformamide: application of cylindrical particle surface-controlled dissolution theory. Phys Chem Chem Phys, 8 (5). pp. 633-641.

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Abstract

A surface-controlled dissolution of cylindrical solid particles model is applied to potassium carbonate, sodium bicarbonate and sodium carbonate in dimethylformamide at elevated temperatures. Previously published data for the dissolution of potassium carbonate is interpreted assuming a cylindrical rather than a spherical shape of the particles, the former representing a closer approximation to the true shape of the particles as revealed by scanning electron microscopy. The dissolution kinetics of sodium carbonate and sodium bicarbonate in dimethylformamide at 100 degrees C were investigated via monitoring of the deprotonation of 2-cyanophenol with dissolved solid to form the 2-cyanophenolate anion that was detected with UV-visible spectroscopy. From fitting of experimental results to theory, the dissolution rate constant, k, for the dissolutions of potassium carbonate, sodium bicarbonate and sodium carbonate in dimethylformamide at 100 degrees C were found to have the values of (1.0 +/- 0.1) x 10(-7) mol cm(-2) s(-1), (5.5 +/- 0.3) x 10(-9) mol cm(-2) s(-1) and (9.7 +/- 0.8) x 10(-9) mol cm(-2) s(-1), respectively.

Item Type: Article
Authors :
NameEmailORCID
Forryan, CLUNSPECIFIEDUNSPECIFIED
Compton, RGUNSPECIFIEDUNSPECIFIED
Klymenko, OVo.klymenko@surrey.ac.ukUNSPECIFIED
Brennan, CMUNSPECIFIEDUNSPECIFIED
Taylor, CLUNSPECIFIEDUNSPECIFIED
Lennon, MUNSPECIFIEDUNSPECIFIED
Date : 7 February 2006
Identification Number : https://doi.org/10.1039/b512463h
Uncontrolled Keywords : Adsorption, Carbonates, Chemistry, Pharmaceutical, Diffusion, Dimethylformamide, Kinetics, Microscopy, Electron, Scanning, Particle Size, Phenols, Potassium, Sodium Bicarbonate, Solubility, Spectrophotometry, Ultraviolet, Temperature
Related URLs :
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 13:57
Last Modified : 17 May 2017 15:14
URI: http://epubs.surrey.ac.uk/id/eprint/840932

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