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A novel approach to the simulation of electrochemical mechanisms involving acute reaction fronts at disk and band microelectrodes.

Klymenko, OV, Svir, I, Oleinick, A and Amatore, C (2012) A novel approach to the simulation of electrochemical mechanisms involving acute reaction fronts at disk and band microelectrodes. Chemphyschem, 13 (3). pp. 845-859.

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Abstract

A new simulation algorithm is presented for describing the dynamics of diffusion reactions at the most common microelectrode 1D (planar, cylindrical, spherical) and 2D geometries (band, disk) for electrochemical mechanisms of any complexity and involving fast homogeneous reactions of any kind. A series of typical electrochemical mechanisms that create the most severe simulation difficulties is used to establish the exceptional performance and accuracy of this algorithm, which stem from the combination of (quasi)conformal transformation of space and a new method for auto-adaptive grid compression.

Item Type: Article
Authors :
NameEmailORCID
Klymenko, OVo.klymenko@surrey.ac.ukUNSPECIFIED
Svir, IUNSPECIFIEDUNSPECIFIED
Oleinick, AUNSPECIFIEDUNSPECIFIED
Amatore, CUNSPECIFIEDUNSPECIFIED
Date : February 2012
Identification Number : https://doi.org/10.1002/cphc.201100825
Related URLs :
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 13:56
Last Modified : 17 May 2017 15:14
URI: http://epubs.surrey.ac.uk/id/eprint/840912

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