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A new strategy for simulation of electrochemical mechanisms involving acute reaction fronts in solution under spherical or cylindrical diffusion

Klymenko, OV, Oleinick, AI, Svir, I and Amatore, C (2012) A new strategy for simulation of electrochemical mechanisms involving acute reaction fronts in solution under spherical or cylindrical diffusion Russian Journal of Electrochemistry, 48 (6). pp. 593-599.

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Abstract

In this paper we present a combined simulation approach for solving complex electrochemical kinetic problems at (hemi)spherical and (hemi)cylindrical electrodes based on the simultaneous application of analytical conformal coordinate transformations to accurately treat the diffusional transport and adaptive grid compression to locally increase the accuracy of the approximation of acute reaction fronts. This strategy is shown to be very efficient and leads to extremely accurate results both for steady state and transient situations and is equally powerful for both pure diffusion and that complicated by severe kinetic distortions. © Pleiades Publishing, Ltd., 2012.

Item Type: Article
Authors :
NameEmailORCID
Klymenko, OVo.klymenko@surrey.ac.ukUNSPECIFIED
Oleinick, AIUNSPECIFIEDUNSPECIFIED
Svir, IUNSPECIFIEDUNSPECIFIED
Amatore, CUNSPECIFIEDUNSPECIFIED
Date : 1 June 2012
Identification Number : https://doi.org/10.1134/S1023193512060055
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 13:56
Last Modified : 17 May 2017 15:14
URI: http://epubs.surrey.ac.uk/id/eprint/840910

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