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Metal-organic framework materials with ultrahigh surface areas: is the sky the limit?

Farha, OK, Eryazici, I, Jeong, NC, Hauser, BG, Wilmer, CE, Sarjeant, AA, Snurr, RQ, Nguyen, ST, Yazaydın, A and Hupp, JT (2012) Metal-organic framework materials with ultrahigh surface areas: is the sky the limit? J Am Chem Soc, 134 (36). pp. 15016-15021.

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Abstract

We have synthesized, characterized, and computationally simulated/validated the behavior of two new metal-organic framework (MOF) materials displaying the highest experimental Brunauer-Emmett-Teller (BET) surface areas of any porous materials reported to date (∼7000 m(2)/g). Key to evacuating the initially solvent-filled materials without pore collapse, and thereby accessing the ultrahigh areas, is the use of a supercritical CO(2) activation technique. Additionally, we demonstrate computationally that by shifting from phenyl groups to "space efficient" acetylene moieties as linker expansion units, the hypothetical maximum surface area for a MOF material is substantially greater than previously envisioned (∼14600 m(2)/g (or greater) versus ∼10500 m(2)/g).

Item Type: Article
Authors :
NameEmailORCID
Farha, OKUNSPECIFIEDUNSPECIFIED
Eryazici, IUNSPECIFIEDUNSPECIFIED
Jeong, NCUNSPECIFIEDUNSPECIFIED
Hauser, BGUNSPECIFIEDUNSPECIFIED
Wilmer, CEUNSPECIFIEDUNSPECIFIED
Sarjeant, AAUNSPECIFIEDUNSPECIFIED
Snurr, RQUNSPECIFIEDUNSPECIFIED
Nguyen, STUNSPECIFIEDUNSPECIFIED
Yazaydın, AUNSPECIFIEDUNSPECIFIED
Hupp, JTUNSPECIFIEDUNSPECIFIED
Date : 12 September 2012
Identification Number : 10.1021/ja3055639
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 12:33
Last Modified : 17 May 2017 12:33
URI: http://epubs.surrey.ac.uk/id/eprint/835792

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