University of Surrey

Test tubes in the lab Research in the ATI Dance Research

Synthesis and characterisation of the garnet-related Li ion conductorl Li5Nd3Sb2O12

Percival, JD, Kendrick, E and Slater, PR (2008) Synthesis and characterisation of the garnet-related Li ion conductorl Li5Nd3Sb2O12 Materials Research Bulletin, 43 (3). pp. 765-770.

Full text not available from this repository.

Abstract

In this paper the synthesis, conductivity, and structure of the garnet-related Li ion conductor, Li5Nd3Sb2O12, are reported. As for the related Li5La3M2O12 (M = Nb, Ta) materials, this phase shows high Li ion conductivity, with a conductivity at 300 degrees C of 9.2 x 10(-3) S cm(-1). Structural studies using neutron diffraction indicate a cubic unit cell, space group Ia-3d, with Li located in two partially occupied sites. One of the sites is the traditional garnet structure tetrahedral site, while the other Li site is considerably more distorted. Although the latter is nominally a six coordinate site, a close inspection suggests that the coordination could be described as distorted tetrahedral, with the remaining two bonds being significantly longer (approximate to 2.6 angstrom)

Item Type: Article
Authors :
NameEmailORCID
Percival, JDjulia.percival@surrey.ac.ukUNSPECIFIED
Kendrick, EUNSPECIFIEDUNSPECIFIED
Slater, PRUNSPECIFIEDUNSPECIFIED
Date : 4 March 2008
Identification Number : https://doi.org/10.1016/j.materresbull.2007.04.002
Uncontrolled Keywords : lithium battery, garnet, lithium ion conductor
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 12:21
Last Modified : 17 May 2017 12:21
URI: http://epubs.surrey.ac.uk/id/eprint/834993

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year


Information about this web site

© The University of Surrey, Guildford, Surrey, GU2 7XH, United Kingdom.
+44 (0)1483 300800