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The synthesis of pseudo-geminal, pseudo-ortho and ortho hydroxy-oxazolinyl[2.2]paracyclophanes for use as ligands in asymmetric catalysis

Bolm, C and Whelligan, DK (2006) The synthesis of pseudo-geminal, pseudo-ortho and ortho hydroxy-oxazolinyl[2.2]paracyclophanes for use as ligands in asymmetric catalysis Adv Synth Catal, 348 (15). pp. 2093-2100.

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Abstract

Synthetic routes to pseudo-geminal, pseudo-ortho and ortho hydroxy-oxazolinyl-[2.2]paracyclophanes (and the diastereoisomers of each) for use as N,O ligands in asymmetric catalysis have been devised. The substitution pattern was found to have a strong effect on the rate and enantioselectivity of the formed catalyst in the addition of diethylzinc to benzaldehyde.

Item Type: Article
Authors :
NameEmailORCID
Bolm, CUNSPECIFIEDUNSPECIFIED
Whelligan, DKd.whelligan@surrey.ac.ukUNSPECIFIED
Date : October 2006
Identification Number : 10.1002/adsc.200600233
Uncontrolled Keywords : asymmetric catalysis, organozinc compounds, oxazolines, paracyclophanes, SCHIFF-BASE LIGANDS, ELECTROPHILIC SUBSTITUTION, DIETHYLZINC ADDITION, MACRO RINGS, PLANAR, ALDEHYDES, RESOLUTION, CHIRALITY, PURE, <2.2>PARACYCLOPHANES
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 11:59
Last Modified : 17 May 2017 15:00
URI: http://epubs.surrey.ac.uk/id/eprint/833512

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