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New strong organic acceptors by cycloaddition of TCNE and TCNQ to donor-substituted cyanoalkynes

Reutenauer, P, Kivala, M, Jarowski, PD, Boudon, C, Gisselbrecht, J-P, Gross, M and Diederich, F (2007) New strong organic acceptors by cycloaddition of TCNE and TCNQ to donor-substituted cyanoalkynes Chemical Communications, 46. pp. 4898-4900.

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Abstract

Donor-substituted 1,1,2,4,4-pentacyanobuta-1,3-dienes and a cyclohexa-2,5-diene-1,4-diylidene-expanded derivative were prepared by a [2 + 2] cycloaddition of tetracyanoethene (TCNE) or 7,7,8,8-tetracyanoquinodimethane (TCNQ) to anilino-substituted cyanoalkynes, followed by retro-electrocyclisation; they feature intense bathochromically-shifted intramolecular chargetransfer bands and undergo their first one-electron reductions at potentials similar to those reported for TCNE and TCNQ.

Item Type: Article
Authors :
NameEmailORCID
Reutenauer, PUNSPECIFIEDUNSPECIFIED
Kivala, MUNSPECIFIEDUNSPECIFIED
Jarowski, PDp.d.jarowski@surrey.ac.ukUNSPECIFIED
Boudon, CUNSPECIFIEDUNSPECIFIED
Gisselbrecht, J-PUNSPECIFIEDUNSPECIFIED
Gross, MUNSPECIFIEDUNSPECIFIED
Diederich, FUNSPECIFIEDUNSPECIFIED
Date : January 2007
Identification Number : https://doi.org/10.1039/b714731g
Related URLs :
Depositing User : Symplectic Elements
Date Deposited : 17 May 2017 11:49
Last Modified : 17 May 2017 11:49
URI: http://epubs.surrey.ac.uk/id/eprint/832892

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