Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry
Boyer, C, Soeriyadi, AH, Roth, PJ, Whittaker, MR and Davis, TP (2011) Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry CHEMICAL COMMUNICATIONS, 47 (4). pp. 1318-1320.
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Abstract
In this communication, we report on a new route to the functionalization of ATRP polymers exploiting their halide end-groups, which were converted successfully into reactive disulfide end-groups, using sodium methanethiosulfonate. The resultant disulfide-terminated polymers could then be reacted with different functional thiols to yield functional polymers exploiting either thiol/disulfide exchange chemistry or thiol/ene ‘‘click’’ reactions.
Item Type: | Article | ||||||||||||||||||
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Subjects : | subj_Chemistry | ||||||||||||||||||
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Date : | 1 January 2011 | ||||||||||||||||||
Identification Number : | 10.1039/c0cc03815f | ||||||||||||||||||
Copyright Disclaimer : | Copyright 2011 Royal Society of Chemistry | ||||||||||||||||||
Uncontrolled Keywords : | Science & Technology, Physical Sciences, Chemistry, Multidisciplinary, Chemistry, CHEMISTRY, MULTIDISCIPLINARY, TRANSFER RADICAL POLYMERIZATION, BROMO CLICK CHEMISTRY, TELECHELIC OLIGOMERS, RAFT-POLYMERS, POLYSTYRENE, MACROMONOMERS, DISULFIDE, ROUTE | ||||||||||||||||||
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Depositing User : | Symplectic Elements | ||||||||||||||||||
Date Deposited : | 25 May 2016 14:25 | ||||||||||||||||||
Last Modified : | 25 May 2016 14:25 | ||||||||||||||||||
URI: | http://epubs.surrey.ac.uk/id/eprint/810832 |
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