Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry

Boyer, C, Soeriyadi, AH, Roth, PJ, Whittaker, MR and Davis, TP (2011) Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry CHEMICAL COMMUNICATIONS, 47 (4). pp. 1318-1320.

	Text 14_2011_Boyer-ATRP-ChemComm.pdf - Version of Record Restricted to Repository staff only Available under License : See the attached licence file. Download (736kB)
Preview	Text (licence) SRI_deposit_agreement.pdf Available under License : See the attached licence file. Download (33kB) | Preview

Abstract

In this communication, we report on a new route to the functionalization of ATRP polymers exploiting their halide end-groups, which were converted successfully into reactive disulfide end-groups, using sodium methanethiosulfonate. The resultant disulfide-terminated polymers could then be reacted with different functional thiols to yield functional polymers exploiting either thiol/disulfide exchange chemistry or thiol/ene ‘‘click’’ reactions.

Item Type:	Article
Subjects :	subj_Chemistry
Divisions :	Surrey research (other units)
Authors :	Boyer, C, Soeriyadi, AH, Roth, PJ, Whittaker, MR and Davis, TP
Date :	1 January 2011
DOI :	10.1039/c0cc03815f
Copyright Disclaimer :	Copyright 2011 Royal Society of Chemistry
Uncontrolled Keywords :	Science & Technology, Physical Sciences, Chemistry, Multidisciplinary, Chemistry, CHEMISTRY, MULTIDISCIPLINARY, TRANSFER RADICAL POLYMERIZATION, BROMO CLICK CHEMISTRY, TELECHELIC OLIGOMERS, RAFT-POLYMERS, POLYSTYRENE, MACROMONOMERS, DISULFIDE, ROUTE
Related URLs :	Author
Depositing User :	Symplectic Elements
Date Deposited :	25 May 2016 14:25
Last Modified :	24 Jan 2020 12:54
URI:	http://epubs.surrey.ac.uk/id/eprint/810832

Actions (login required)

View Item

Downloads