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Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry

Boyer, C, Soeriyadi, AH, Roth, PJ, Whittaker, MR and Davis, TP (2011) Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry CHEMICAL COMMUNICATIONS, 47 (4). pp. 1318-1320.

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Abstract

In this communication, we report on a new route to the functionalization of ATRP polymers exploiting their halide end-groups, which were converted successfully into reactive disulfide end-groups, using sodium methanethiosulfonate. The resultant disulfide-terminated polymers could then be reacted with different functional thiols to yield functional polymers exploiting either thiol/disulfide exchange chemistry or thiol/ene ‘‘click’’ reactions.

Item Type: Article
Subjects : subj_Chemistry
Authors :
AuthorsEmailORCID
Boyer, CUNSPECIFIEDUNSPECIFIED
Soeriyadi, AHUNSPECIFIEDUNSPECIFIED
Roth, PJUNSPECIFIEDUNSPECIFIED
Whittaker, MRUNSPECIFIEDUNSPECIFIED
Davis, TPUNSPECIFIEDUNSPECIFIED
Date : 1 January 2011
Identification Number : 10.1039/c0cc03815f
Copyright Disclaimer : Copyright 2011 Royal Society of Chemistry
Uncontrolled Keywords : Science & Technology, Physical Sciences, Chemistry, Multidisciplinary, Chemistry, CHEMISTRY, MULTIDISCIPLINARY, TRANSFER RADICAL POLYMERIZATION, BROMO CLICK CHEMISTRY, TELECHELIC OLIGOMERS, RAFT-POLYMERS, POLYSTYRENE, MACROMONOMERS, DISULFIDE, ROUTE
Related URLs :
Depositing User : Symplectic Elements
Date Deposited : 25 May 2016 14:25
Last Modified : 25 May 2016 14:25
URI: http://epubs.surrey.ac.uk/id/eprint/810832

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