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Thiol-reactive Passerini-methacrylates and polymorphic surface functional soft matter nanoparticles via ethanolic RAFT dispersion polymerization and post-synthesis modification

Pei, Y, Noy, J-M, Roth, PJ and Lowe, AB (2015) Thiol-reactive Passerini-methacrylates and polymorphic surface functional soft matter nanoparticles via ethanolic RAFT dispersion polymerization and post-synthesis modification POLYMER CHEMISTRY, 6 (11). pp. 1928-1931.

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Abstract

RAFT dispersion polymerization (RAFTDP) is used to prepare reactive nanoparticles via the incorporation of Passerini-derived methacrylic comonomers containing pentafluorophenyl (PFP) groups. Copolymerization of 2-(dimethylamino)ethyl methacrylate with a Passerini comonomer gives copolymers suitable as macro-CTAs for ethanolic RAFTDP of 3-phenylpropyl methacrylate. Reaction of the PFP residues with functional thiols offers an approach for preparing surface modified nanoparticles.

Item Type: Article
Subjects : Chemistry
Divisions : Faculty of Engineering and Physical Sciences > Chemistry
Authors :
AuthorsEmailORCID
Pei, YUNSPECIFIEDUNSPECIFIED
Noy, J-MUNSPECIFIEDUNSPECIFIED
Roth, PJUNSPECIFIEDUNSPECIFIED
Lowe, ABUNSPECIFIEDUNSPECIFIED
Date : 1 January 2015
Identification Number : 10.1039/c4py01558d
Copyright Disclaimer : Copyright 2015 Royal Society of Chemistry
Uncontrolled Keywords : Science & Technology, Physical Sciences, Polymer Science, BLOCK-COPOLYMER COMPOSITION, MOLECULAR-WEIGHT, NANO-OBJECTS
Related URLs :
Depositing User : Symplectic Elements
Date Deposited : 19 May 2016 11:12
Last Modified : 19 May 2016 11:13
URI: http://epubs.surrey.ac.uk/id/eprint/810468

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