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Does the gamma Polymorph of Glycine Nucleate Faster? A Quantitative Study of Nucleation from Aqueous Solution

Little, LJ, Sear, RP and Keddie, JL (2015) Does the gamma Polymorph of Glycine Nucleate Faster? A Quantitative Study of Nucleation from Aqueous Solution Crystal Growth and Design, 15 (11). pp. 5345-5354.

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Abstract

We advance the quantitative study of nucleation by combining the study of hundreds of samples, with statistical tests for reproducibility, and for well-defined nucleation rates. Unlike in most previous work, we find that in the samples that nucleate after the first hour of our experiment the equilibrium glycine polymorph predominates over the alpha form.

Item Type: Article
Divisions : Faculty of Engineering and Physical Sciences > Physics
Authors :
AuthorsEmailORCID
Little, LJUNSPECIFIEDUNSPECIFIED
Sear, RPUNSPECIFIEDUNSPECIFIED
Keddie, JLUNSPECIFIEDUNSPECIFIED
Date : 1 November 2015
Identification Number : 10.1021/acs.cgd.5b00938
Uncontrolled Keywords : Science & Technology, Physical Sciences, Technology, Chemistry, Multidisciplinary, Crystallography, Materials Science, Multidisciplinary, Chemistry, Materials Science, CRYSTAL NUCLEATION, CRYSTALLIZATION, GROWTH, EMULSIONS, KINETICS, ALPHA, MECHANISMS, DROPLETS, INSIGHTS, RATES
Related URLs :
Additional Information : This document is the Accepted Manuscript version of a Published Work that appeared in final form in Crystal Growth and Design, copyright ©2015 American Chemical Society after peer review and technical editing by the publisher.To access the final edited and published work see 10.1021/acs.cgd.5b00938.
Depositing User : Symplectic Elements
Date Deposited : 12 Jan 2016 13:50
Last Modified : 01 Nov 2016 02:08
URI: http://epubs.surrey.ac.uk/id/eprint/809518

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