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Preparation, X-ray crystal structures and properties of α-(BEDT-TTF)[Fe(phen)(NCS)[· 2CHCl and (BEDT-TTF)]Cr(isoq) (NCS)[ (phen = 1,10-phenanthroline; Isoq = isoquinoline)

Setifi, F, Golhen, S, Ouahab, L, Turner, SS and Day, P (2002) Preparation, X-ray crystal structures and properties of α-(BEDT-TTF)[Fe(phen)(NCS)[· 2CHCl and (BEDT-TTF)]Cr(isoq) (NCS)[ (phen = 1,10-phenanthroline; Isoq = isoquinoline) CrystEngComm, 4 (1). pp. 1-6.

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Abstract

This paper reports the preparation, X-ray crystal structure, conducting and magnetic properties of α-(BEDT-TTF)]Fe(phen) (NCS)[ (1) [BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene, phen = 1,10-phenanthroline] together with the crystal structure of (BEDT-TTF)]Cr (isoq)(NCS)[ (2) (isoq = isoquinoline) for which the physical properties have been reported previously. Compound 1 crystallizes in the triclinic space group P1 (no. 2), a = 12.1528(1), b = 16.8269(3), c = 27.0703(4) Å, α = 95.726(1), β = 95.834(1), γ = 108.080(1)°, Z = 4, R = 0.0610 for 9764 reflections with I > 2σ(I); 2 crystallizes in the monoclinic space group P2/c (no. 14), a =10.623(5), b = 14.656(8), c = 12.701(7) Å, β = 100.19(2)°, Z = 2, R = 0.0737 for 2747 reflections with I > 2σ(I). The magnetic and transport properties have shown that compound 1 is a paramagnetic semiconductor with σ = 2.2 × 10 Ω cm. © 2002 The Royal Society of Chemistry.

Item Type: Article
Authors :
AuthorsEmailORCID
Setifi, FUNSPECIFIEDUNSPECIFIED
Golhen, SUNSPECIFIEDUNSPECIFIED
Ouahab, LUNSPECIFIEDUNSPECIFIED
Turner, SSUNSPECIFIEDUNSPECIFIED
Day, PUNSPECIFIEDUNSPECIFIED
Date : 2002
Identification Number : https://doi.org/10.1039/b110466g
Depositing User : Symplectic Elements
Date Deposited : 28 Mar 2017 13:27
Last Modified : 28 Mar 2017 13:27
URI: http://epubs.surrey.ac.uk/id/eprint/805045

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