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Structures and physical properties of BEDT-TTF salts containing channels of protons

Akutsu-Sato, A, Akutsu, H, Turner, SS, Le Pevelen, D, Day, P, Light, ME, Hursthouse, MB, Akutagawa, T and Nakamura, T (2003) Structures and physical properties of BEDT-TTF salts containing channels of protons Synthetic Metals, 135-13. pp. 597-598.

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Abstract

Charge transfer salts with stoichiometry β″-(BEDT-TTF) [M(CO),](18-crown-6 ether)(9HO), where M= Cr, Ga or Fe and x= 2 or 3 are reported. Their structures suggest that proton migration is possible. Variable temperature resistivity measurements on the Cr salt show metallic behaviour down to 180K. Magnetic susceptibility of the Cr salt is paramagnetic down to 1.8 K. Preliminary impedance measurements suggest that the proton conductivities of the Cr and Ga salts are the order of 10 S cm at 300 K. © 2003 Elsevier Science B.V. All rights reserved.

Item Type: Article
Authors :
NameEmailORCID
Akutsu-Sato, AUNSPECIFIEDUNSPECIFIED
Akutsu, HUNSPECIFIEDUNSPECIFIED
Turner, SSUNSPECIFIEDUNSPECIFIED
Le Pevelen, DUNSPECIFIEDUNSPECIFIED
Day, PUNSPECIFIEDUNSPECIFIED
Light, MEUNSPECIFIEDUNSPECIFIED
Hursthouse, MBUNSPECIFIEDUNSPECIFIED
Akutagawa, TUNSPECIFIEDUNSPECIFIED
Nakamura, TUNSPECIFIEDUNSPECIFIED
Date : 4 April 2003
Identification Number : 10.1016/S0379-6779(02)00781-6
Depositing User : Symplectic Elements
Date Deposited : 28 Mar 2017 13:22
Last Modified : 31 Oct 2017 15:14
URI: http://epubs.surrey.ac.uk/id/eprint/802891

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