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Crystal structure and magnetic properties of a one-dimensional polymer [Mn(im2-py)(tp)(HO)]·1.25HO

Li, L, Liu, S, Liao, D, Jiang, Z, Yan, S and Turner, SS (2003) Crystal structure and magnetic properties of a one-dimensional polymer [Mn(im2-py)(tp)(HO)]·1.25HO Journal of Coordination Chemistry, 56 (5). pp. 383-388.

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Abstract

A new manganese(II) complex [Mn(im2-py)(tp)(HO)]·1.25HO (im2-py = 2-(2′-pyridyl)-4,4,5,5-tetramethyl-imidazoline-1-oxyl and tp = terephthalato dianion) has been synthesized and characterized structurally and magnetically. The crystal structure consists of neutral chains of manganese(II) ions linked by the terephthalate ligand. Variable temperature magnetic susceptibility data exhibit a weak antiferromagnetic coupling between the manganese(II) ion and the imino nitroxide radical.

Item Type: Article
Authors :
AuthorsEmailORCID
Li, LUNSPECIFIEDUNSPECIFIED
Liu, SUNSPECIFIEDUNSPECIFIED
Liao, DUNSPECIFIEDUNSPECIFIED
Jiang, ZUNSPECIFIEDUNSPECIFIED
Yan, SUNSPECIFIEDUNSPECIFIED
Turner, SSUNSPECIFIEDUNSPECIFIED
Date : 20 March 2003
Identification Number : https://doi.org/10.1080/0095897031000092403
Depositing User : Symplectic Elements
Date Deposited : 28 Mar 2017 13:22
Last Modified : 28 Mar 2017 13:22
URI: http://epubs.surrey.ac.uk/id/eprint/802888

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