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β″-(BEDT-TTF)[(HO)Cr(CO )]CHCl: Effect of included solvent on the structure and properties of a conducting molecular charge-transfer salt

Rashid, S, Turner, SS, Le Pevelen, D, Day, P, Light, ME, Hursthouse, MB, Firth, S and Clark, RJH (2001) β″-(BEDT-TTF)[(HO)Cr(CO )]CHCl: Effect of included solvent on the structure and properties of a conducting molecular charge-transfer salt Inorganic Chemistry, 40 (20). pp. 5304-5306.

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Abstract

The new charge-transfer salt β″-(BEDT-TTF)[(HO)Cr(CO )]S, where BEDT-TTF = bis-(ethylenedithio)tetrathiafulvalene and S = CHCl has a broad metal-insulator transition at approximately 150 K. This differs from similar salts in the BEDT-TTF tris(oxalato) metalate series, notably the superconducting materials with S = PhCN and the salt with S = CHN, which has a sharp metal-insulator transition.

Item Type: Article
Authors :
NameEmailORCID
Rashid, SUNSPECIFIEDUNSPECIFIED
Turner, SSUNSPECIFIEDUNSPECIFIED
Le Pevelen, DUNSPECIFIEDUNSPECIFIED
Day, PUNSPECIFIEDUNSPECIFIED
Light, MEUNSPECIFIEDUNSPECIFIED
Hursthouse, MBUNSPECIFIEDUNSPECIFIED
Firth, SUNSPECIFIEDUNSPECIFIED
Clark, RJHUNSPECIFIEDUNSPECIFIED
Date : 24 September 2001
Identification Number : 10.1021/ic010484f
Depositing User : Symplectic Elements
Date Deposited : 28 Mar 2017 13:22
Last Modified : 31 Oct 2017 15:14
URI: http://epubs.surrey.ac.uk/id/eprint/802882

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