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TTF based charge transfer salts of [M(NCS)(CHN)] where M = Cr, Fe and CHN = isoquinoline; observation of bulk ferrimagnetic order

Turner, SS, Michaut, C, Durot, S, Day, P, Elbrich, T and Hursthouse, MB (2000) TTF based charge transfer salts of [M(NCS)(CHN)] where M = Cr, Fe and CHN = isoquinoline; observation of bulk ferrimagnetic order Journal of the Chemical Society, Dalton Transactions (6). pp. 905-909.

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Abstract

Three new charge transfer salts of BEDT-TTF and TTF with the counter ions [M(NCS)4(C9H7N)J~ (M = Cr, Fe; C9H7N = isoquinoline) are described. The materials are prepared by standard electrocrystallisation techniques. The nature of the anion is verified in the crystal structure of the salt [C9H8N][Cr(NCS)4(C9H7N)]-C,2H24O6-H2O which is used as the electrolyte when M = Cr. All of the charge transfer salts display long range ferrimagnetic order originating from the interaction between M (5=3/2 or 5= 5/2) and the donor (5= 1/2). The measured critical temperatures are 4.2 K (BEDT-TTF, M = Cr), 4.5 K (BEDT-TTF, M = Fe) and 8.9 K (TTF, M = Cr). Each of the compounds also shows a modest magnetic hysteresis of 338, 18 and 75 Oe for BEDT-TTF salts of M = Cr, Fe and the TTF salt of Cr, respectively. © The Royal Society of Chemistry 2000.

Item Type: Article
Authors :
AuthorsEmailORCID
Turner, SSUNSPECIFIEDUNSPECIFIED
Michaut, CUNSPECIFIEDUNSPECIFIED
Durot, SUNSPECIFIEDUNSPECIFIED
Day, PUNSPECIFIEDUNSPECIFIED
Elbrich, TUNSPECIFIEDUNSPECIFIED
Hursthouse, MBUNSPECIFIEDUNSPECIFIED
Date : 2000
Identification Number : https://doi.org/10.1039/a910259k
Depositing User : Symplectic Elements
Date Deposited : 28 Mar 2017 13:22
Last Modified : 28 Mar 2017 13:22
URI: http://epubs.surrey.ac.uk/id/eprint/802875

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