Ion-radical salts: A new type of molecular ferrimagnet
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Turner, SS and Day, P (2005) Ion-radical salts: A new type of molecular ferrimagnet Journal of Materials Chemistry, 15 (1). pp. 23-25.
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Abstract
Long-range ferrimagnetic order in which one magnetic sub-lattice is formed from partly-occupied p-orbitals and the other from d-orbitals can be achieved in molecular ion-radical salts where the cations are oxidised organo-chalcogen donors and the anions are 3d-metal complexes containing both N-bonded NCS and planar N-heterocyclic ligands. Overlaps between p-orbitals of the radical cations and those of the heterocycle are implicated in the cation-anion exchange pathway.
Item Type: | Article |
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Divisions : | Surrey research (other units) |
Authors : | Turner, SS and Day, P |
Date : | 7 January 2005 |
DOI : | 10.1039/b412696n |
Depositing User : | Symplectic Elements |
Date Deposited : | 28 Mar 2017 13:22 |
Last Modified : | 24 Jan 2020 12:10 |
URI: | http://epubs.surrey.ac.uk/id/eprint/802701 |
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