Ion-radical salts: A new type of molecular ferrimagnet

Turner, SS and Day, P (2005) Ion-radical salts: A new type of molecular ferrimagnet Journal of Materials Chemistry, 15 (1). pp. 23-25.

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Abstract

Long-range ferrimagnetic order in which one magnetic sub-lattice is formed from partly-occupied p-orbitals and the other from d-orbitals can be achieved in molecular ion-radical salts where the cations are oxidised organo-chalcogen donors and the anions are 3d-metal complexes containing both N-bonded NCS and planar N-heterocyclic ligands. Overlaps between p-orbitals of the radical cations and those of the heterocycle are implicated in the cation-anion exchange pathway.

Item Type:	Article
Divisions :	Surrey research (other units)
Authors :	Turner, SS and Day, P
Date :	7 January 2005
DOI :	10.1039/b412696n
Depositing User :	Symplectic Elements
Date Deposited :	28 Mar 2017 13:22
Last Modified :	24 Jan 2020 12:10
URI:	http://epubs.surrey.ac.uk/id/eprint/802701

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