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Ion-radical salts: A new type of molecular ferrimagnet

Turner, SS and Day, P (2005) Ion-radical salts: A new type of molecular ferrimagnet Journal of Materials Chemistry, 15 (1). pp. 23-25.

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Long-range ferrimagnetic order in which one magnetic sub-lattice is formed from partly-occupied p-orbitals and the other from d-orbitals can be achieved in molecular ion-radical salts where the cations are oxidised organo-chalcogen donors and the anions are 3d-metal complexes containing both N-bonded NCS and planar N-heterocyclic ligands. Overlaps between p-orbitals of the radical cations and those of the heterocycle are implicated in the cation-anion exchange pathway.

Item Type: Article
Authors :
Turner, SS
Day, P
Date : 7 January 2005
DOI : 10.1039/b412696n
Depositing User : Symplectic Elements
Date Deposited : 28 Mar 2017 13:22
Last Modified : 31 Oct 2017 15:14

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