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Novel purely organic conductor with an aminoxyl radical, α-(BEDT-TTF)(PO-CONHCHSO) ·2HO (PO = 2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl free radical)

Akutsu, H, Yamashita, S, Yamada, J-I, Nakatsuji, S and Turner, SS (2008) Novel purely organic conductor with an aminoxyl radical, α-(BEDT-TTF)(PO-CONHCHSO) ·2HO (PO = 2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl free radical) Chemistry Letters, 37 (8). pp. 882-883.

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Abstract

A novel bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)-based salt with an aminoxyl radical 2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl (PO) has been prepared. The salt has α-type 2-D conducting sheets and is a semiconductor with ρ = 26 Ω·cm and E = 0.31 eV. The temperature dependence of the magnetic susceptibility suggests that both the aminoxyl radical and the BEDT-TTF layer have local spin moments at room temperature. Copyright © 2008 The Chemical Society of Japan.

Item Type: Article
Authors :
NameEmailORCID
Akutsu, HUNSPECIFIEDUNSPECIFIED
Yamashita, SUNSPECIFIEDUNSPECIFIED
Yamada, J-IUNSPECIFIEDUNSPECIFIED
Nakatsuji, SUNSPECIFIEDUNSPECIFIED
Turner, SSUNSPECIFIEDUNSPECIFIED
Date : 5 August 2008
Identification Number : 10.1246/cl.2008.882
Depositing User : Symplectic Elements
Date Deposited : 28 Mar 2017 13:22
Last Modified : 31 Oct 2017 15:15
URI: http://epubs.surrey.ac.uk/id/eprint/802687

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