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A new ferrocene-containing charge-transfer salt, (TTF) [Fe(C H -CH(CH )NHCOCH SO ) ]

Kanbayashi, N, Akutsu, H, Yamada, J-I, Nakatsuji, S and Turner, SS (2012) A new ferrocene-containing charge-transfer salt, (TTF) [Fe(C H -CH(CH )NHCOCH SO ) ] Inorganic Chemistry Communications, 21. pp. 122-124.

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A novel ferrocene-containing dianion, Fe(C H - CH(CH )NHCOCH SO ) (1), has been prepared. The oxidation potential of the PPh salt is + 0.35 V (vs. SCE in PhCN), indicating that it is a stronger donor than TTF (tetrathiafulvalene) by + 0.03 V. The dianion provided a TTF salt, the structure and physical properties of which are reported. © 2012 Elsevier B.V. All rights reserved.

Item Type: Article
Authors :
Kanbayashi, N
Akutsu, H
Yamada, J-I
Nakatsuji, S
Turner, SS
Date : July 2012
DOI : 10.1016/j.inoche.2012.04.028
Additional Information : NOTICE: this is the author’s version of a work that was accepted for publication in Inorganic Chemistry Communications. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Inorganic Chemistry Communications, 21, July 2012, DOI 10.1016/j.inoche.2012.04.028
Depositing User : Symplectic Elements
Date Deposited : 23 Sep 2013 14:00
Last Modified : 31 Oct 2017 15:15

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