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Sulfur, normally a poison, strongly promotes chemoselective catalytic hydrogenation: stereochemistry and reactivity of crotonaldehyde on clean and S-modified Cu(111).

Chiu, ME, Kyriakou, G, Williams, FJ, Watson, DJ, Tikhov, MS and Lambert, RM (2006) Sulfur, normally a poison, strongly promotes chemoselective catalytic hydrogenation: stereochemistry and reactivity of crotonaldehyde on clean and S-modified Cu(111). Chem Commun (Camb) (12). pp. 1283-1285.

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Abstract

Sulfur adatoms strongly activate the otherwise inert Cu(111) surface towards chemoselective hydrogenation of crotonaldehyde by electronically perturbing and strongly tilting the reactant.

Item Type: Article
Authors :
AuthorsEmailORCID
Chiu, MEUNSPECIFIEDUNSPECIFIED
Kyriakou, GUNSPECIFIEDUNSPECIFIED
Williams, FJUNSPECIFIEDUNSPECIFIED
Watson, DJUNSPECIFIEDUNSPECIFIED
Tikhov, MSUNSPECIFIEDUNSPECIFIED
Lambert, RMUNSPECIFIEDUNSPECIFIED
Date : 28 March 2006
Identification Number : https://doi.org/10.1039/b517154g
Uncontrolled Keywords : Aldehydes, Catalysis, Copper, Hydrogenation, Stereoisomerism, Sulfur, Surface Properties
Related URLs :
Depositing User : Symplectic Elements
Date Deposited : 28 Mar 2017 13:51
Last Modified : 28 Mar 2017 13:51
URI: http://epubs.surrey.ac.uk/id/eprint/794983

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