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Krypton irradiation damage in Nd-doped zirconolite and perovskite

Davoisne, C, Stennett, MC, Hyatt, NC, Peng, Nianhua, Jeynes, Christopher and Lee, WE (2011) Krypton irradiation damage in Nd-doped zirconolite and perovskite Journal of Nuclear Materials, 415 (1). pp. 67-73.

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Abstract

Understanding the effect of radiation damage and noble gas accommodation in potential ceramic hosts for plutonium disposition is necessary to evaluate their long-term behaviour during geological disposal. Polycrystalline samples of Nd-doped zirconolite and Nd-doped perovskite were irradiated ex situ with 2 MeV Kr+ at a dose of 5 1015 ions cm2 to simulate recoil of Pu nuclei during alpha decay. The feasibility of thin section preparation of both pristine and irradiated samples by Focused Ion Beam sectioning was demonstrated. After irradiation, the Nd-doped zirconolite revealed a well defined amorphous region separated from the pristine material by a thin (40–60 nm) damaged interface. The zirconolite lattice was lost in the damaged interface, but the fluorite sublattice was retained. The Nd-doped perovskite contained a defined irradiated layer composed of an amorphous region surrounded by damaged but still crystalline layers. The structural evolution of the damaged regions is consistent with a change from orthorhombic to cubic symmetry. In addition in Nd-doped perovskite, the amorphisation dose depended on crystallographic orientation and possibly sample configuration (thin section or bulk). Electron Energy Loss Spectroscopy revealed Ti remained in the 4+ oxidation state but there was a change in Ti coordination in both Nd-doped perovskite and Nd-doped zirconolite associated with the crystalline to amorphous transition.

Item Type: Article
Divisions : Faculty of Engineering and Physical Sciences > Electronic Engineering > Advanced Technology Institute > Ion Beam Centre
Authors :
NameEmailORCID
Davoisne, CUNSPECIFIEDUNSPECIFIED
Stennett, MCUNSPECIFIEDUNSPECIFIED
Hyatt, NCUNSPECIFIEDUNSPECIFIED
Peng, NianhuaN.Peng@surrey.ac.ukUNSPECIFIED
Jeynes, Christopherc.jeynes@surrey.ac.ukUNSPECIFIED
Lee, WEUNSPECIFIEDUNSPECIFIED
Date : 2011
Identification Number : 10.1016/j.jnucmat.2011.05.043
Copyright Disclaimer : © 2011. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
Depositing User : Symplectic Elements
Date Deposited : 06 Jan 2015 15:51
Last Modified : 19 Jul 2017 16:38
URI: http://epubs.surrey.ac.uk/id/eprint/7867

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