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X-ray photoelectron spectroscopy study of electron and spatial structure of mono- and binuclear Ni(II) carboxylate complexes with nitrogen-containing ligands

Kochur, AG, Ivanova, TM, Hinder, SJ, Watts, JF, Sidorov, AA, Kiskin, MA, Novotortsev, VM and Eremenko, IL (2011) X-ray photoelectron spectroscopy study of electron and spatial structure of mono- and binuclear Ni(II) carboxylate complexes with nitrogen-containing ligands JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 184 (8-10). 501 - 507. ISSN 0368-2048

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Abstract

Ni3s, Ni3p and Ni2p x-ray photoelectron spectra of mono-and binuclear carboxylate complexes of nickel with various geometry of metal ions environment are obtained. The spectra are calculated in an isolated ion approximation. The dependence of the spectral profiles and the structure of the charge-transfer satellites on the structure of the immediate environment of nickel atoms is established. The data obtained support the results of X-ray diffraction and magnetic studies.

Item Type: Article
Additional Information: NOTICE: this is the author’s version of a work that was accepted for publication in Journal of Electron Spectroscopy and Related Phenomena. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Electron Spectroscopy and Related Phenomena, 184(8-10), November 2011, DOI 10.1016/j.elspec.2011.08.005
Uncontrolled Keywords: Science & Technology, Technology, Spectroscopy, XPS, Nickel (II) carboxylate complexes, Electron and spatial structure, TRIMETHYLACETATE COMPLEXES, SPECTRA
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Divisions: Faculty of Engineering and Physical Sciences > Mechanical Engineering Sciences
Depositing User: Symplectic Elements
Date Deposited: 11 Jul 2012 18:07
Last Modified: 23 Sep 2013 19:33
URI: http://epubs.surrey.ac.uk/id/eprint/712193

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