The development of controllable complex curing agents for epoxy resins - Part 3. An investigation of the shelf life and thermal dissociation behaviour of bis(acetanilido)tris(acetato)dicuprate(II)
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Hamerton, I, Emsley, AM, Hay, JN, Herman, H, Howlin, BJ and Jepson, P (2006) The development of controllable complex curing agents for epoxy resins - Part 3. An investigation of the shelf life and thermal dissociation behaviour of bis(acetanilido)tris(acetato)dicuprate(II) JOURNAL OF MATERIALS CHEMISTRY, 16 (3). 255 - 265. ISSN 0959-9428
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Official URL: http://dx.doi.org/10.1039/b510393b
Abstract
Bis(acetanilido)-tris(acetato)dicuprate(II), [Cu2(C7H8N2O)2(CH3CO2−)3], is incorporated into MY721, a commercial epoxy resin recognised as an ‘industry standard’. Infrared spectroscopy and thermogravimetry are employed to examine the structure and thermal dissociation behaviour of the newly prepared complex. Multivariate analysis techniques (e.g. principal components analysis) are used to examine the spectral data to corroborate the dissociation temperature. The shelf life and cure characteristics of the commercial epoxy/curing agent formulation are determined using differential scanning calorimetry and vibrational spectroscopy.
| Item Type: | Article |
|---|---|
| Additional Information: | Definitive version at: http://pubs.rsc.org/en/content/articlepdf/2006/jm/b510393b Copyright 2010 Royal Society of Chemistry |
| Uncontrolled Keywords: | Science & Technology, Physical Sciences, Technology, Chemistry, Physical, Materials Science, Multidisciplinary, Chemistry, Materials Science, 4 PHENYLENE RINGS, MATHEMATICAL-MODELS, CURE, KINETICS, BLENDS, ANTHRANILAMIDE, COPPER(II), COBALT(II), DICYANATE, SYSTEMS |
| Divisions: | Faculty of Engineering and Physical Sciences > Chemistry |
| Related URLs: | |
| ID Code: | 326437 |
| Deposited By: | Symplectic Elements |
| Deposited On: | 23 Mar 2012 14:07 |
| Last Modified: | 17 Apr 2013 02:35 |
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